Electrocatalysis of chlorine evolution on different materials and its influence on the performance of an electrochemical reactor for indirect oxidation of pollutants

Two different Ti/Pt–Ir materials (commercial and home made) and Ti/PdO + Co₃O₄ were investigated for their electrocatalytic properties versus Cl₂ evolution reaction. The materials were used in a batch electrochemical reactor to treat biologically recalcitrant di-azo compound. An electrochemically driven oxidation, mediated by a Cl₂/Cl⁻ couple, proved efficient for destruction of this complex organic molecule, causing cleavage of the conjugated double bonds and destruction of unsatured bonds. Both Ti/Pt–Ir materials performed well; lower kinetics obtained with the Ti/PdO + Co₃O₄ anode was caused by adsorption of the model compound, evidenced in preliminary voltammetric measurements. The dye oxidation reaction followed the second order kinetics with partial orders in the model compound and (time varying) chlorine concentrations equal to one. Specific energy consumption of 3.12 kWh m⁻³ proved the process more economic than the homogeneous phase oxidation.     

Photocatalytic Property and Electronic Structure of Lanthanide-based Oxysulfides

Lanthanide-based oxysulfides and sulfide, LnTaO_3.5S_0.5, Ln₁₀OS₁₄ (Ln = La, Pr, Nd, Sm) and La₄In₅S₁₃, were successively synthesized by sulfurization in a flowing H₂S. The sulfurization decreased the band-gap energies from >4 eV to <3eV, because of the formation of occupied S3p orbitals on the top of valence band. In accordance with the small band gap, the H₂ evolution from a 0.01 M Na₂S and 0.01 M Na₂SO₃ solution system was observed under irradiation of light up to >500 nm. The rate of H₂ evolution under light irradiation of >500 nm increased in the order of Ni/LaTaO_3.5S_0.5 < Ru/La₁₀OS₁₄ < Pt/La₄In₅S₁₃.     

Performance modeling and evaluation of data/voice services in wireless networks

Application-level performance is a key to the adoption and success of the CDMA 2000. To predict this performance in advance, a detailed end-to-end simulation model of a CDMA network is built to include application traffic characteristics, network architecture, network element details using the proposed simulation methodology. We assess the user-perceived application performance when a RAN and a CN adopt different transport architectures such as ATM and IP. To evaluate the user-perceived quality of voice service, we compare the end-to-end packet delay for different vocoder schemes such as G.711, G.726 (PCM), G.726 (ADPCM), and vocoder bypass scheme. By the simulation results, the vocoder bypass scenario shows 30% performance improvement over the others. We also compare the quality of voice service with and without DPS scheduling scheme. We know that DPS scheme keep the voice delay bound even if the service traffic is high. For data packet performance, HTTP v.1.1 shows better performance than that of HTTP v.1.0 due to the pipelining and TCP persistent connection. We may conclude that IP transport technology is better solution for higher FER environment since the packet overhead of IP is smaller than that of ATM for web browsing data traffic, while it shows opposite effect to the small size voice packet in RAN architecture. We show that the 3G-1X EV-DO system gives much better packet delay performance than 3G-1X RTT. The main conclusion is that end-to-end application-level performance is affected by various elements and layers of the network and thus it must be considered in all phases of the development process. Jae-Hyun Kim He received the B.S., M.S., and Ph.D. degrees, all in computer science and engineering, from Hanyang University, Ansan, Korea, in 1991, 1993, and 1996 respectively. In 1996, he was with the Communication Research Laboratory, Tokyo, Japan, as a Visiting Scholar. From April 1997 to October 1998, he was a post-doctoral fellow at the department of electrical engineering, University of California, Los Angeles. From November 1998 to February 2003, he worked as a member of technical staff in Performance Modeling and QoS management department, Bell laboratories, Lucent Technologies, Holmdel, NJ. He has been with the department of electrical engineering, Ajou University, Suwon, Korea, as an assistant professor since 2003. His research interests include QoS issues and cross layer optimization for high-speed wireless communication. Dr. Kim was the recipient of the LGIC Thesis Prize and Samsung Human-Tech Thesis Prize in 1993 and 1997, respectively. He is a member of the Korean Institute of Communication Sciences (KICS), Korea Institute of Telematics and Electronis (KITE), Korea Information Science Society (KISS), and IEEE. Hyun-Jin Lee received the B.S. degree in electrical engineering from Ajou University, Suwon, Korea, in 2004, and is working toward the M.S. degree and Ph. D. degree in electrical engineering at Ajou University. He has been awarded Samsung Human-Tech Thesis Prize in 2004. His research interests QoS, especially network optimization and wireless packet scheduling. He is a member of the KICS. Sung-Min Oh received the B.S. and M. S. degrees in electrical engineering form Ajou University, Suwon, Korea, in 2004, and is working toward the Ph. D. degree in electrical engineering at Ajou University. His research interests QoS performance analysis and 4G network. He is a member of the KICS. Sung-Hyun Cho received his B.S., M.S., and Ph.D. in computer science and engineering from Hanyang University, Korea, in 1995, 1997, and 2001, respectively. From 2001 to 2005, he has been with Samsung Advanced Institute of Technology, where he has been engaged in the design and standardization of MAC and upper layers of B3G, IEEE 802.16e, and WiBro systems. He is currently a MAC part leader in the telecommunication R&D center of Samsung Electronics. His research interests include 4G air interface design, radio resource management, cross layer design, and handoff in wireless systems.     

数控超声加工的初步工艺试验

介绍在经过数控化改造的两坐标超声加工机床上所进行数控超声加工的初步工艺试验,并讨论试验结果。     

苏北-南黄海盆地构造演化

苏北及南黄海盆地是由多期、多类盆地叠加的复合残留盆地,地质概况基本相似,成因演化近同,自元古界下扬子板块形成后,主要经历了古-中生代地台、中生代前陆盆地、走滑拉分盆地时期以及新生代断陷、坳陷盆地时期.在古生代-中生代发展过程中是一个整体,晚白垩世盆地演化出现分化,发育伸展盆地群,形成一系列叠置在中、古生代盆地之上的箕状断陷,箕状断陷的发育及分布明显受中-古生界内部先存逆冲断裂的控制.     

Exploring the landscape of modern academic psychology: Finding and filling the holes.

Like any other domain of human activity, psychology has its fads and fashions. One consequence of fads is an overconcentration of resources on specific problems or approaches, which leaves other important problems or approaches (holes) underappreciated and understudied. This article is primarily about different factors (such as negativity bias, polarization of positions, focus on internal causes of behavior, dedication to a narrow view of what science is) that result in holes and about explorations of some of these holes that have interested the author. Psychologists should look more in the holes left behind by current enthusiasms. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

塔里木盆地西部层序地层格架控制下的石炭系沉积成岩演化特征

根据高频旋回层序在长周期旋回层序内的有序叠加方式可在研究区石炭系中划分出3个Ⅲ级旋回层序和2个Ⅱ级旋回层序.其中Ⅲ₃和Ⅲ₃旋回层序为海侵体系域,Ⅲ₂为高水位体系域,它们共同构成了研究区的层序地层格架并且控制着沉积相和生储盖组合的时空展布特征.由于受成岩历史差异性和不同成岩环境的影响,石炭系碎屑岩和碳酸盐岩储集岩成岩特征和储集性能在巴楚隆起区和麦盖提斜坡区均存在明显差异,且分布在斜坡区的储层物性明显优于隆起区同层位的储层,是近期有利的的勘探区域.      

基于进化规划的自适应IIR滤波

针对基于梯度下降算法的自适应IIR滤波器（AIIRF）具有潜在的不稳定性和性能指标函数容易陷入局部极小而导致性能下降等问题，本文将进化规划用于AI－IRF的优化设计，不仅解决了AIIRF系统稳定性问题，而且有效地实现了滤波器性能指标函数的全局寻优和快速收敛，同时允许大动态范围的输入号。计算机仿真结果验证了基于进化规划算法的AIIRF的性能优于基于梯度算法的AIIRF，尤其对高阶、极点靠近单位圆的自适应IIR滤波器。     

关于决策支持系统的结构与进化

本文在总结作者开发决策支持系统的实践经验的基础上，从ＤＳＳ的结构分析入手，探讨了ＤＳＳ的进化问题，首先通过软件开发方式，程序设计风范，人工智能道路和系统科学发展等方面的深入剖析，指出了进化能力的强弱是ＤＳＳ成败的关键。其次展开了关于ＤＳＳ结构的研究，提出了ＤＳＳ的外延结构和内涵结构的新概念并进行了比较。随后讨论了ＤＳＳ的进化问题，分析了传统的第一代决策支持系统存在的缺陷，阐述了第二代和第三代决策支     

Object-extending class transformations

Reorganisation and evolution of class hierarchies is important for object-oriented system development and has received considerable attention in the literature. The contributions of this paper are: (1) a formal study of a set of extension relations and transformations on class hierarchies; (2) a presentation of a small set of primitive transformations which form a minimal and complete basis for the extension relations; and (3) an analysis of the impact of these transformations at the object level.The study leads to a better understanding of evolution and reuse of object-oriented software and class hierarchies. It also provides a terminology and a means of classification for design reuse. The theory presented in this paper is based on the Demeter data model, which gives a concise mathematical foundation for classes and their inheritance and part-of relationships. Parts of the theory have been implemented in the Demeter System ^TM C++, a CASE tool for object-oriented design and programming.